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SOFC Mixed Metal Oxides

 
SOFC Electrode Materials
Component Material compounds Composition Characteristic
Electrolyte ZrO2 compound Y2O3 stabilized ZrO3 Standard material
    Y2O3-ZrO2-Al2O3 High-strength
    Sc2O3 stabilized ZrO2 High-conductivity
    Sc2O3-ZrO2-Al2O3 Reduction of transition temperature
    YSZ-Pr surf Electron conductivity
  CeO2 compound (CeO2)0.3(SmO1.5)0.3 Actuation at low temperature
    (CeO2)0.3(GdO1.5)0.2  
    (CeO2)0.3(YO1.5)0.2  
  Bi2O3 compound (Bi2O3)0.3(SrO)0.2  
  Ln2Ti2O7 compound Ln2(TiZr)2O7  
  (Ln : rare-earth element) (Ln=Sm, Gd, Y)  
  LnAlO3 compound (LnCa)(AlGd)O3  
  (Ln : rare-earth element) (Ln=Pr, Nd)  
  LaGaO3 compound La0.3Sr0.2Ga0.3Mg0.2O3 High-conductivity
  ACeO3 compound BaCe0.3Y0.2O3-_ H+ ion conductor
  (A=Ca, Ba) SrCe0.95Yb0.05O3-_  
    Ba(CeGd)O3-_  
    Ba(CeDy)O3-_  
Anode Ni compound Ni-YSZ Standard material
    Ni-MgO-YSZ Long-term stabilization
    Ni-TiO2-YSZ  
    Ni-CeO2 Low overvoltage
    Ni-(CeO2)0.3(SmO1.5)0.2 High-property modification
    Ni-PrO2  
  Ru compound Ru-YSZ Low overvoltage, High-property modification
  TiO2 - YSZ compound TiO2-YSZ Stabilize under low oxygen partial pressure.
  (LaCa)CrO3 compound (La0.3Ca0.2)CrO3 High-property modification
Cathode LnMnO3 compound (LaSr)MnO3 Standard material
    (PrSr)MnO3 Low overvoltage at low temperature
    LnAMnO3 Low cost (use La intermediate purification
    (Ln=La, Pr, Ce, A=Ca, Sr) product)
    {(La0.6Y0.4)0.3Sr0.2}MnO3 Reduction of thermal expansion coefficient
    (GdA)MnO3 (A=Ca, Sr) Reduction of reaction with YSZ
  LnCoO3 compound (LaSr)CoO3 High conductivity
    (LaSr)(CoFe)O3 Low overvoltage at low temperature
    (GdSr)CoO3 Reduction of reaction with YSZ
  YFeO3 compound (Yca)FeO3 Reduction of reaction with YSZ
Interconnector LnCrO3 compound (LaA)(CrB)O3 Standard material
/ Separator (Ln : rare-earth element) (A=Ca, Sr, B=Co, Ni)  
    La(CrMg)3 Low reduction of lattice expansion
    (LaCa)(CrCoFeNi)O3 Improvement of sintering character
    LnCrO3 (Ln=La, Ce, Pr) Low cost
  Cr compound (CrFe)5(Y2O3)1 Alloyed metal of low thermal expansion

 
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